for sure, Arcgis already have Geostatistic, but I think its not enough for you, ehehehehehe
I will name all the software , here you go :
Geo-EAS (free)
GSLIB: Geostatistical Software Library (free)
GS+ - from Gamma Design Software
Gstat - geostatistical modeling, prediction, and simulation
SpaceStat - from TerraSeer
S+SpatialStats Module - from Insightful
Matlab and Fortran software for spatial lattice regression models (free)
PASSaGE: Pattern Analysis, Spatial Statistics and Geographic Exegesis
okay